Synthesis, thermal properties, and biological study of metal(II) nicotinamide complexes containing fumarate dianion and fumaric acid: Crystal structure of [Ni(H2O)4(nia)2](fum)·(H2fum)

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dc.contributor.authorTella, Adedibu C.
dc.contributor.authorOwalude, Samson O.
dc.contributor.authorMehlana, Gift
dc.contributor.authorOlatunji, Sunday J.
dc.contributor.authorAdetitun, David O.
dc.contributor.authorKolawole, Mathew O.
dc.contributor.authorSimon, Nzikahyel
dc.contributor.authorAlimi, Lukman O.
dc.date.accessioned2019-10-30T11:52:48Z
dc.date.available2019-10-30T11:52:48Z
dc.date.issued2017-02-28
dc.description.abstractNew divalent transition metal nicotinamide (nia) complexes containing fumarate (fum) dianion and fumaric acid (H2fum), [M(H2O)4(nia)2](fum)¢(H2fum) [M = Co (1), Cu (2), and Ni (3)] have been synthesized. The compounds were characterized by elemental analyses, infrared, UV-vis, XRPD, and TGA. Structural analysis of 3 using single-crystal X-ray diffraction technique revealed that the Ni(II) ion is coordinated by four aqua and two nia ligands in an octahedral geometry. The structure of 3 is completed with fumarate (fum2¡) dianion acting as a counterion while fumaric acid (H2fum) is present as a molecule of solvation. The three complexes were investigated for biological activities.en_US
dc.identifier.uriDOI: 10.1080/15533174.2016.1212234
dc.identifier.urihttp://hdl.handle.net/123456789/3164
dc.language.isoenen_US
dc.publisherTaylor and Francis, UK.en_US
dc.subjectFumarate complexesen_US
dc.subjectnicotinamideen_US
dc.subjectcrystal structureen_US
dc.subjectXRPD analysisen_US
dc.subjectbiological activityen_US
dc.titleSynthesis, thermal properties, and biological study of metal(II) nicotinamide complexes containing fumarate dianion and fumaric acid: Crystal structure of [Ni(H2O)4(nia)2](fum)·(H2fum)en_US
dc.typeArticleen_US

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