Hexakis(benzonitrile)ruthenium(II) bis[tetrafluoroborate(1-)]: a precursor to ruthenium organometallic compounds
| dc.contributor.author | Owalude, Samson O. | |
| dc.contributor.author | Odebunmi, Ezekiel O. | |
| dc.contributor.author | Eke, Uche B. | |
| dc.contributor.author | Tella, Adedibu C. | |
| dc.contributor.author | Rheingold, Arnold L. | |
| dc.contributor.author | Jackson, Randy | |
| dc.contributor.author | Suib, Steven L. | |
| dc.date.accessioned | 2019-10-30T11:55:52Z | |
| dc.date.available | 2019-10-30T11:55:52Z | |
| dc.date.issued | 2015-11-14 | |
| dc.description.abstract | The new compound, [Ru(NCC6H5)6][BF4]2, has been synthesized by reaction of the polymeric species [{RuCl2(COD)}x] (COD = 1,5-cyclooctadiene) with benzonitrile under reflux and characterized by elemental analysis, IR, NMR spectroscopic analyses, and single crystal X-ray diffraction. The Ru(II) atom is coordinated by six N atoms from six benzonitrile ligands in distorted octahedralc oordination geometry. The compound was crystallized in the monoclinic space group P21/c with unit-cell dimensions a = 10.7536(11) A ° , b = 18.6582(18) A °, c = 20.311(2) A ° , b = 91.864(2) , V = 4073.2(7) A ° 3 and final R of 0.0429. | en_US |
| dc.identifier.issn | DOI 10.1007/s11164-013-1491-7 | |
| dc.identifier.uri | http://hdl.handle.net/123456789/3177 | |
| dc.language.iso | en | en_US |
| dc.publisher | Springer | en_US |
| dc.subject | Ruthenium | en_US |
| dc.subject | Benzonitrile | en_US |
| dc.subject | Spectroscopic analysis | en_US |
| dc.subject | Reaction intermediate | en_US |
| dc.subject | X-ray crystallography | en_US |
| dc.title | Hexakis(benzonitrile)ruthenium(II) bis[tetrafluoroborate(1-)]: a precursor to ruthenium organometallic compounds | en_US |
| dc.type | Article | en_US |