Crystal Structure of (Cycloocta-1,5-diene)tris(hydrazine)hydridoruthenium( II) tetraphenylborate
| dc.contributor.author | OWALUDE, Samson O. | |
| dc.contributor.author | EKE, Uche B. | |
| dc.contributor.author | ODEBUNMI, Ezekiel O. | |
| dc.contributor.author | NESTEROV, Vladimir N. | |
| dc.contributor.author | MEIJBOOM, Reinout | |
| dc.contributor.author | COVILLE, Neil J. | |
| dc.date.accessioned | 2019-10-22T08:25:44Z | |
| dc.date.available | 2019-10-22T08:25:44Z | |
| dc.date.issued | 2012-04-18 | |
| dc.description.abstract | The salt [RuH(COD)(H2NNH2)3][BPh4] (2) (COD = cycloocta-1,5-diene and BPh4 = tetraphenylborate) was prepared by reacting the polymeric species [{Ru(COD)Cl2}x] (1; x > 2) with hydrazine hydrate in refluxing ethanol. The obtained crystal was characterized by single-crystal X-ray analysis. The compound crystallizes in the monoclinic space group P21/n with unit-cell dimensions a = 9.7449(8)Å, b = 32.881(3)Å, c = 18.6962(16)Å, b = 99.571(10)˚, V = 5907.3(9)Å3 and Z = 8. The ruthenium has a distorted octahedral geometry with two formula units comprising two cations and two anions in the asymmetric unit. | en_US |
| dc.identifier.uri | http://hdl.handle.net/123456789/2986 | |
| dc.language.iso | en | en_US |
| dc.publisher | The Japan Society for Analytical Chemistry | en_US |
| dc.subject | Crystal Structure | en_US |
| dc.subject | Cycloocta-1,5-diene | en_US |
| dc.subject | hydrazine | en_US |
| dc.subject | hydridoruthenium(II) | en_US |
| dc.title | Crystal Structure of (Cycloocta-1,5-diene)tris(hydrazine)hydridoruthenium( II) tetraphenylborate | en_US |
| dc.type | Article | en_US |