Synthesis, thermal properties, and biological study of metal(II) nicotinamide complexes containing fumarate dianion and fumaric acid: Crystal structure of [Ni(H2O)4(nia)2](fum)·(H2fum)

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dc.contributor.authorADEDIBU, TELLA
dc.contributor.authorOWALUDE, SAMSON
dc.contributor.authorMEHLANA, GIFT
dc.contributor.authorOLATUNJI, SUNDAY
dc.contributor.authorADETITUN, DAVID
dc.contributor.authorKOLAWOLE, OLATUNJI
dc.contributor.authorNZIKAHYEL, SIMON
dc.contributor.authorALIMI, LUKMAN
dc.date.accessioned2018-03-27T15:22:15Z
dc.date.available2018-03-27T15:22:15Z
dc.date.issued2017
dc.description.abstractNew divalent transition metal nicotinamide (nia) complexes containing fumarate (fum) dianion and fumaric acid (H2fum), [M(H2O)4(nia)2](fum)·(H2fum) [M = Co (1), Cu (2), and Ni (3)] have been synthesized.The compounds were characterized by elemental analyses, infrared, UV-vis, XRPD, and TGA. Structural analysis of 3 using single-crystal X-ray diffraction technique revealed that the Ni(II) ion is coordinated by four aqua and two nia ligands in an octahedral geometry. The structure of 3 is completed with fumarate (fum2−) dianion acting as a counterion while fumaric acid (H2fum) is present as a molecule of solvation. The three complexes were investigated for biological activities.en_US
dc.identifier.citation1en_US
dc.identifier.urihttp://hdl.handle.net/123456789/186
dc.language.isoenen_US
dc.publisherTaylor and Francisen_US
dc.relation.ispartofseries47;6
dc.subjectFumarate complexesen_US
dc.subjectNicotinamideen_US
dc.subjectCrystal structureen_US
dc.subjectXRPD analysisen_US
dc.subjectbiological activityen_US
dc.titleSynthesis, thermal properties, and biological study of metal(II) nicotinamide complexes containing fumarate dianion and fumaric acid: Crystal structure of [Ni(H2O)4(nia)2](fum)·(H2fum)en_US
dc.typeArticleen_US

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