Synthesis of new ruthenium(II) complexes containing isocyanide and labile nitrile ligands

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dc.contributor.authorOwalude, S. O.
dc.contributor.authorTella, A.C.
dc.contributor.authorEke, U. B.
dc.contributor.authorOdebunmi, E.O.
dc.date.accessioned2019-10-30T11:55:05Z
dc.date.available2019-10-30T11:55:05Z
dc.date.issued2017-10-30
dc.description.abstractA new ruthenium(II) complex containing both acetonitrile and propionitrile moieties as coordinating ligands has been prepared. The treatment of the polymer [{RuCl2(COD)}x], (COD = cycloocta-1,5-diene) (1) with a mixture of acetonitrile and propionitrile under reflux produced a new precursor [RuCl2(COD)(NCCH3)(CH3CH2CN)] (2). Also the compound [RuCl2L4] (3) (L = 2,6-dimethylphenylisocyanide) was prepared through a ligand exchange of a derivative of 1, [RuCl2(COD)(NCCH3)2] (4), with 2,6-dimethylphenylisocyanide. The two compounds were characterized by elemental analyses, IR and NMR (1H and 13C) measurements. The ruthenium in both compounds has distorted octahedral coordination geometry.en_US
dc.identifier.urihttp://hdl.handle.net/123456789/3174
dc.language.isoenen_US
dc.publisherAhmadu Bello University, Zaria, Nigeriaen_US
dc.subjectNitrile ligandsen_US
dc.subjectruthenium(II)en_US
dc.subject2,6-dimethylphenylisocyanideen_US
dc.subjectspectroscopic analysisen_US
dc.titleSynthesis of new ruthenium(II) complexes containing isocyanide and labile nitrile ligandsen_US
dc.typeArticleen_US

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