Synthesis and structural characterization of some ruthenium(II) alkoxide complexes

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dc.contributor.authorOwalude, S. O.
dc.contributor.authorOdebunmi, E. O.
dc.contributor.authorEke, U. B.
dc.contributor.authorTella, A. C.
dc.date.accessioned2019-10-21T13:35:13Z
dc.date.available2019-10-21T13:35:13Z
dc.date.issued2014-01-03
dc.descriptionmain articleen_US
dc.description.abstractThe complex [RuCl2(COD)(OR)2] (COD = cyclo-octa-1,5-diene and R = CH3 or C2H5) has been prepared by treatment of the polymeric specie [{RuCl2(COD)}x]) with appropriate LiOR solution and has been characterized by elemental analysis, IR and lH NMR spectroscopic analyses. The reaction of the alkoxide complex with two or more equivalent of phosphine ligands gave the complex [Ru(COD)(OR)2L2] (R = CH3 or C2H5; L = methoxyphenyldiphenylphosphine and tri(m-tolyl)phosphine) while the subsequent reaction with diphenylphosphine yielded [Ru(OR)2(Ph2P)4] (R = C2H5). Spectroscopic and elemental analysis data revealed symmetric alkoxide bridged diruthenium phosphine complexes.en_US
dc.identifier.issn2408 – 4840
dc.identifier.urihttp://hdl.handle.net/123456789/2958
dc.language.isoenen_US
dc.publisherFaculty of Physical Sciences, University of Ilorinen_US
dc.subjectRutheniumen_US
dc.subjectalkoxideen_US
dc.subjectcycloocta-1,5-dieneen_US
dc.subjectphosphine ligandsen_US
dc.titleSynthesis and structural characterization of some ruthenium(II) alkoxide complexesen_US
dc.typeArticleen_US

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