SELECTIVE ADSORPTION OF Fe (II) OVER Zn (II) FROM PHARMACEUTICAL WASTEWATER
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Date
2021-11
Journal Title
Journal ISSN
Volume Title
Publisher
COAST JOURNAL OF THE SCHOOL OF SCIENCE
Abstract
Abstract
This work focused on the utilization of termite mound clay and activated carbon prepared from
groundnuts pod for the selective removal of Fe (II) over Zn (II) from Pharmaceutical Wastewater. The initial
concentration of Fe (II) [0.46 mg/l] and Zn (II) [0.10mg/l] in the pharmaceutical wastewater were
determined using Atomic Absorption Spectrophotometer (AAS). Scanning Electron Microscopy (SEM)
technique, Fourier transforms infrared (FT-IR) spectroscopy, X-Ray uorescence (XRF) and X-ray
diffraction (XRD) were conducted to investigate the adsorbent features. A preliminary experiment was
carried out to determine the suitable adsorbent for optimization studies. Optimization study using Box
Behnken experimental design in Response Surface Methodology were employed. The coded levels
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selected includes adsorbent loading between 0.05- 0.15 g, temperatures 25 - 45 C and time 30 - 90 mins.
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At Optimal condition, 6.6 pH value, the temperature of 25 C, contact time of 90 mins and adsorbent
dosage of 0.1 g, the Fe (II) in the Pharmaceutical Wastewater was removed by 95.72 %. The Langmuir
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adsorption isotherm model was found to have R of 0.9997. The adsorption capacity of the adsorbent was
found to be 0.44 mg/g. Adsorption of Fe (II) onto groundnut pod activated carbon and termite mound clay
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was best described by the pseudo rst order kinetic model (R = 1.000). The termite mound clay and the
activated carbonized groundnuts pod shows an effective adsorption towards the removal of the targeted
pollutant from the pharmaceutical wastewater.
Keywords: adsorption, Box Behnken design, groundnuts pod, pharmaceutical wastewater, termite
mound.
Description
Keywords
Citation
Box Behnken design, groundnuts pod, pharmaceutical wastewater, termite mound.